Coordination polymers from mild condition reactions of copper(II) carboxylates with pyrazole (Hpz). Influence of carboxylate basicity on the self-assembly of the [Cu₃(μ₃-OH)(μ-pz)₃]²⁺ secondary building unit

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• 作者：Sara Massignani^a ; Rebecca Scatena^a ; ^b ; Arianna Lanza^b ; ; Magda Monari^c ; ; Francesca Condello^d ; Fabrizio Nestola^e ; Claudio Pettinari^d ; Federico Zorzi^e ; Luciano Pandolfo^a ;
• 关键词：Coordination polymers ; Self-assembly ; Copper(II) ; Carboxylates ; Pyrazole
• 刊名：Inorganica Chimica Acta
• 出版年：2017
• 出版时间：30 January 2017
• 年：2017
• 卷：455
• 期：part_P2
• 页码：618-626
• 全文大小：1344 K
• 卷排序：455

文摘

Cu carboxylates and pyrazole in alcohols yield trinuclear triangular CuII assemblies. Trinuclear triangular CuII moieties self-assemble to give coordination polymers. Basicity of carboxylates is the determining key for the trinuclear assembly. Coordination polymers are obtained through cheap and simple procedures.