Luminescent thione/phosphane mixed-ligand copper(I) complexes: The effect of thione on structural properties

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• 作者：Alexandra Koutsari ; Fani Karasmani ; Eleni Kapetanaki ; Dini Iflakhah Zainuddin ; Antonios G. Hatzidimitriou ; Panagiotis Angaridis ; ^{panosangaridis@chem.auth.gr} ; Paraskevas Aslanidis
• 关键词：Copper(I) complexes ; Phosphanes ; Heterocyclic thiones ; Crystal structures ; Luminescence
• 刊名：Inorganica Chimica Acta
• 出版年：2017
• 出版时间：24 March 2017
• 年：2017
• 卷：458
• 期：Complete
• 页码：138-145
• 全文大小：1581 K
• 卷排序：458

文摘

Synthesis and X-ray structures of copper(I) complexes with a mixed set of halide, PPh3 and heterocyclic thione ligands. Two distinct types of structural motifs: binuclear centrosymmetric thione-bridged or mononuclear complexes. All complexes are photoluminescent in the solid state with emission maxima in the 400–490 nm range.