Platinum(II) and copper(I) 1-(2-diphenylphosphino-1-naphthyl) isoquinoline complexes: Synthesis and phosphorescence at ambient conditions

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• 作者：Valeri Pawlowski ; Horst Kunkely ; Arnd Vogler
• 关键词：Luminescence ; Phosphorescence ; Platinum(II) ; Copper(I) ; 1-(2-Diphenylphosphino-1-naphthyl)isoquinoline
• 刊名：Inorganica Chimica Acta
• 出版年：2009
• 出版时间：1 January 2009
• 年：2009
• 卷：362
• 期：1
• 页码：226-228
• 全文大小：194 K

文摘

The compounds Pt(quinap)(CN)₂, and [Cu(quinap)I]₂ with quinap = 1-(2-diphenylphosphino-1-naphthyl)isoquinoline were synthesized. Quinap is a bidentate ligand which contains a isoquinoline and an arylphosphine group with CT acceptor properties. Accordingly, the Pt(II) and Cu(I) quinap complexes are characterized by a phosphorescence originating from the lowest-energy MLCT triplets with some IL admixture.