Reactions of chlorosilanes with dioxomolybdenum(VI) complexes

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• 作者：Arzoumanian ; Henri ; Krentzien ; Heinz ; Corao ; Carolina ; Lopez ; Rafael ; Agrifoglio ; Giuseppe
• 刊名：Polyhedron
• 出版年：1995
• 出版时间：September, 1995
• 年：1995
• 卷：14
• 期：20-21
• 页码：2887-2891
• 全文大小：292 K

文摘

Various trialkylchlorosilanes were reacted with a number of molybdenum-oxo complexes in order to establish the main factors which influence the process of addition of the SiCl function across the MoO bond. A novel intermolecular mode of hexaalkyldisiloxane formation was observed in one case.