Anionic N-heterocyclic carbenes: Synthesis, coordination chemistry and applications in homogeneous catalysis

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Anionic N-heterocyclic carbenes: Synthesis, coordination chemistry and applications in homogeneous catalysis

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作者：Alexandre Nasr ; Andrea Winkler ; Matthias Tamm ; ^{m.tamm@tu-bs.de" class="auth_mail" title="E-mail the corresponding author}
关键词：2 ; 2 ; 2-Cryptand ; 4 ; 7 ; 13 ; 16 ; 21 ; 24-hexaoxa-1 ; 10-diazabicyclo[8.8.8]hexacosane ; 12-C-4 ; 1 ; 4 ; 7 ; 10-tetraoxacyclododecane ; 18-C-6 ; 1 ; 4 ; 7 ; 10 ; 13 ; 16-hexaoxacyclooctadecane ; Ac ; acetyl ; Acac ; acetylacetonato ; Au ; gold ; Atm ; atmosphere ; BArF ; tetrakis[3 ; 5-(CF3)2C6H3]borate ; BDE ; bond dissociation energy ; BIm ; bis(imidazolin-2-ylidene-1-yl) ; Bn ; benzyl ; Bp ; bis(1-pyrazolyl)borate ; BTz ; bis(1 ; 2 ; 4-triazol-1-yl) ; ca. ; circa ; Cat ; 1 ; 2-dihydroxybenzene ; CMB ; conjugated mesomeric betaines ; CCMB ; cross conjugated m
刊名：Coordination Chemistry Reviews
出版年：2016
出版时间：1 June 2016
年：2016
卷：316
期：Complete
页码：68-124
全文大小：14524 K

文摘

•: Anionic N-heterocyclic carbenes (NHCs) bear an exo- or endo-cyclic anionic substituent.
•: Anionic NHCs containing delocalized or non-delocalized anionic charges are described.
•: Anionic NHCs react with transition-metal or main-group precursors to afford overall neutral zwitterionic complexes or ate-complexes.
•: Comparison of the catalytic performance of these overall neutral zwitterionic and their cationic congeners is described.

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