Manganese organometallic compounds in homogeneous catalysis: Past, present, and prospects

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Manganese organometallic compounds in homogeneous catalysis: Past, present, and prospects

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作者：Dmitry A. Valyaev^a ; ^b ; ^{dmitry.valyaev@lcc-toulouse.fr" class="auth_mail" title="E-mail the corresponding author} ; Guy Lavigne^a ; ^b ; ¹ ; Noë ; l Lugan^a ; ^b ; ^{noel.lugan@lcc-toulouse.fr" class="auth_mail" title="E-mail the corresponding author}
关键词：acac ; acetylacetonate ; All ; allyl ; An ; methoxyphenyl ; BARF ; tetrakis[3 ; 5-bis(trifluoromethyl)phenyl]borate ; Bn ; benzyl ; Bu ; n-butyl ; Cp ; η5-cyclopentadienyl ; Cp&prime ; η5-methylcyclopentadienyl ; CPE ; controlled potential electrolysis ; CV ; cyclic voltammetry ; Cy ; cyclohexyl ; DCE ; 1 ; 2-dichloroethane ; Dec ; n-decyl ; Dipp ; 2 ; 6-diisopropylphenyl ; DME ; 1 ; 2-dimethoxyethane ; DMF ; dimethylformamide ; DMPU ; 1 ; 3-dimethyl-3 ; 4 ; 5 ; 6-tetrahydro-2(1H)-pyrimidinone ; DMSO ; dimethylsulfoxide ; dpm ; 2 ; 2 ; 6 ; 6-tetramethy
刊名：Coordination Chemistry Reviews
出版年：2016
出版时间：1 February 2016
年：2016
卷：308
期：part_P2
页码：191-235
全文大小：14459 K

文摘

•: Manganese is a good metal for catalysis due to its abundance and biocompatibility.
•: Manganese organometallic complexes do catalyze a broad variety of reactions.
•: Mn catalysts can provide improved chemoselectivity and functional group tolerance.

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