Theoretical and experimental formation of low chlorinated dibenzo-p-dioxins and dibenzofurans in the Fenton oxidation of chlorophenol solutions

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Theoretical and experimental formation of low chlorinated dibenzo-p-dioxins and dibenzofurans in the Fenton oxidation of chlorophenol solutions

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作者：Pablo Ferná ; ndez-Castro ; M. Fresnedo San Romá ; n ; Inmaculada Ortiz ; ^{ortizi@unican.es" class="auth_mail" title="E-mail the corresponding author}
关键词：2-Chlorophenol ; Fenton oxidation ; Dibenzo-p-dioxins ; Dibenzofurans ; Reaction mechanism
刊名：Chemosphere
出版年：2016
出版时间：October 2016
年：2016
卷：161
期：Complete
页码：136-144
全文大小：860 K

文摘

•: Fenton oxidation reports fast degradation kinetics of aqueous 2-CP solutions.
•: Complete mineralization of CP is not reached especially under substoichiometric conditions.
•: The formation of minor byproducts such as PCDD/Fs are observed.
•: High concentrations of DCDD and DCDF have been detected.
•: A mechanism for the formation of low chlorinated PCDD/Fs in aqueous oxidation media is proposed.

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