Effects of the size and Cu modulation of Pd<sub>n</sub> (n </ce:hsp>⩽ </ce:hsp>38) clusters on Hg<sup>0</sup> adsorption

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Effects of the size and Cu modulation of Pd_n (n ⩽ 38) clusters on Hg⁰ adsorption

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作者：Lixia Ling^a ; ^{linglixia@tyut.edu.cn" class="auth_mail" title="E-mail the corresponding author} ; Lili Fan^a ; Xue Feng^a ; Baojun Wang^b ; ^{wangbaojun@tyut.edu.cn" class="auth_mail" title="E-mail the corresponding author} ; Riguang Zhang^b
关键词：Size effect ; Cu modulation ; Hg0 adsorption ; Activated carbon supported Pdn (n ; ⩽ ; 38) clusters
刊名：Chemical Engineering Journal
出版年：2017
出版时间：15 January 2017
年：2017
卷：308
期：Complete
页码：289-298
全文大小：2189 K

文摘

•: AC can enhance the stability of magic clusters Pd_n (n = 4, 6, 8, 13, 19, 23).
•: Pd_n cluster size influences Hg⁰ adsorption greatly, and Pd₁₃/AC is optimal.
•: CuPd₁₂, Cu₂Pd₁₁ and Cu₆Pd₇ bimetallic clusters are relatively easy to obtain.
•: The adsorption of Hg⁰ is affected by Cu doping ratio, and Cu₂Pd₁₁/AC is the best.

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