A fresh look at the thermodynamic consistency of vapour-liquid equilibria data

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• 作者：Jaime Wisniak^a ; ^{wisniak@exchange.bgu.ac.il} ; Juan Ortega^b ; Luis Ferná ; ndez^b
• 关键词：Thermodynamic consistency ; VLE ; Gibbs-Duhem equation ; Herington test ; Kojima test ; Redlich-Kister test ; Van Ness test ; Wisniak test ; McDermott-Ellis test
• 刊名：The Journal of Chemical Thermodynamics
• 出版年：2017
• 出版时间：February 2017
• 年：2017
• 卷：105
• 期：Complete
• 页码：385-395
• 全文大小：1127 K
• 卷排序：105

文摘

The thermodynamic consistency tests commonly used to evaluate VLE data are presented and discussed. Advantages/disadvantages for each one of test are listed using actual examples. All manuscripts should include information about VLE variables and test results. In any case, the Herington test should not be used for VLE data evaluation. Simultaneous application of several tests is recommended.