Assessing the stability of the Co(I) species of two mononuclear dichlorocobalt compounds bearing 2,2′-bipyridine and trans-2-(2′-quiolyl)methylene-3-quinuclidione via <sup>59</sup>Co NMR spectroscopy, electrochemical, and catalyzed proton electroreduction studies

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Assessing the stability of the Co(I) species of two mononuclear dichlorocobalt compounds bearing 2,2′-bipyridine and trans-2-(2′-quiolyl)methylene-3-quinuclidione via ⁵⁹Co NMR spectroscopy, electrochemical, and catalyzed proton electroreduction studies

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作者：Mark A.W. Lawrence ; Alvin A. Holder ; ^{aholder@odu.edu" class="auth_mail" title="E-mail the corresponding author}
关键词：Cobalt(II) ; 59Co NMR spectroscopy ; Electrochemistry ; Electrocatalysis ; Hydrogen production
刊名：Inorganica Chimica Acta
出版年：2016
出版时间：24 February 2016
年：2016
卷：441
期：Complete
页码：157-168
全文大小：2590 K

文摘

•: Electrochemical studies of [Co(bpy)₂Cl₂] and [Co(quin)Cl₂] in CH₃CN-H₂O (4:1, v/v).
•: First solution ⁵⁹Co NMR spectroscopic study of [ⁿBu₄N][Co(bpy)₂(solv)] in CD₃CN-D₂O (4:1, v/v).
•: The quin ligand has a negative influence on the stability of the Co(I) species.
•: The supporting electrolyte influences the electrochemical properties.