Performance of basic mixed oxides for aqueous-phase 5-hydroxymethylfurfural-acetone aldol condensation

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作者：Jennifer Cueto ; Laura Faba ; Eva Dí ; az ; Salvador Ordó ; ñ ; ez ; ^{sordonez@uniovi.es" class="auth_mail" title="E-mail the corresponding author}
关键词：Aldol reaction ; Basic catalysis ; Biomass upgrading ; CC coupling
刊名：Applied Catalysis B: Environmental
出版年：2017
出版时间：February 2017
年：2017
卷：201
期：Complete
页码：221-231
全文大小：1631 K

文摘

class="label">•: Oligomerization reactions, strong adsorption, and reaction reversibility hinders the reaction.
class="label">•: Extent of these undesirable processes is higher than for furfural-acetone condensation.
class="label">•: Selectivity for C15 adduct only significant for Mg-Zr, but lower than for furfural reaction.
class="label">•: Kinetic model considering consecutive reversible reactions yielding C₉ and C₁₅.
class="label">•: Stability in aqueous phase conditioned by the oligomerization reactions, not by catalyst leaching.