Phenol could generate useful hydrated electron for the pollutants remediation.
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With p-benzoquinone as the product, one mole of phenol could eject four moles of hydrated electron via two periods.
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The formation of p-hydroquinone was accomplished by hydrogen abstraction of the adduct with phenoxyl radical as hydrogen acceptor.
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The generation of hydrated electron from the molecular phenol was facilitated by OH− via multiple site electron–proton transfer (MS-EPT) pathway.
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The quantum calculation results were in agreement with the experimental proposal.
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