Cultivar discriminating ability of ANNs on Apulian monocultivar EVOOs was studied.
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Merceological, NIR and 1H NMR data were used as ANNs training sets.
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ANN models based on NMR data showed the highest accuracy in classifying cultivars.
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The most information about cultivars was contained in very few NMR peaks.
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Performance was not influence by the milling method nor the crop year.
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