Intercalated methylene blue between calcium niobate nanosheets by ESD technique for electrocatalytic oxidation of ascorbic acid
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MB cations have been inserted into the interlayer of calcium niobate by ESD method.

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Self-assembly between MB+ and Ca2Nb3O10 nanosheets can be finished in a few minutes.

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MB cations were found to be tilted about 46° against calcium niobate nanosheets.

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MB–Ca2Nb3O10 shows good electrocatalytic activity toward ascorbic acid oxidation.

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