Hydrogen release and uptake in the Li-Zn-N system

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Hydrogen release and uptake in the Li-Zn-N system

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作者：Trang T.T. Nguyen^a ; Daniel Reed^b ; David Book^b ; Paul A. Anderson^a ; ^{p.a.anderson@bham.ac.uk" class="auth_mail" title="E-mail the corresponding author}
关键词：Lithium amide ; Zinc nitride ; Lithium zinc nitride ; Hydrogen absorption/desorption ; Reversible hydrogen storage ; Temperature-programmed desorption with mass spectrometry (TPD&ndash ; MS)
刊名：Journal of Alloys and Compounds
出版年：2015
出版时间：5 October 2015
年：2015
卷：645
期：supp_S1
页码：S295-S298
全文大小：878 K

文摘

•: Reactions of ZnCl₂ + nLiNH₂ gave a mixture of Zn₃N₂ and LiZnN as products.
•: No stable amide chloride, imide chloride or nitride chloride phases were identified.
•: The addition of lithium hydride (LiH) changed the main gaseous product from NH₃ to H₂.
•: Neither pure LiZnN nor Zn₃N₂ could be rehydrogenated under the conditions studied.
•: LiZnN/Zn₃N₂, and LiZnN/LiCl mixtures hydrogenated at 300 °C to form LiNH₂ and Zn metal.

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