A monomeric, heterobimetallic complex with an unsupported Mg-Fe bond

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• 作者：Christopher Birchall ; Graeme J. Moxey ; Jonathan McMaster ; Alexander J. Blake ; William Lewis ; Deborah L. Kays ; ^{deborah.kays@nottingham.ac.uk}
• 关键词：Magnesium ; Iron ; Metal-metal interactions ; N ligands ; Density functional calculations
• 刊名：Inorganica Chimica Acta
• 出版年：2017
• 出版时间：24 March 2017
• 年：2017
• 卷：458
• 期：Complete
• 页码：97-100
• 全文大小：422 K
• 卷排序：458

文摘

An unsupported bond between an alkaline earth element and a transition metal. M-M bond best described by a donor/acceptor model with large ionic contribution. Calculations and spectroscopy identify a predominantly ionic Mg–Fe bond.