The voltammetry of decamethylferrocene and coboltacene in supercritical difluoromethane (R32)

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The voltammetry of decamethylferrocene and coboltacene in supercritical difluoromethane (R32)

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作者：P.N. Bartlett ; ^{p.n.bartlett@soton.ac.uk" class="auth_mail" title="E-mail the corresponding author} ; J. Branch
关键词：Supercritical fluid ; Decamethylferrocene ; Difluoroethane
刊名：Journal of Electroanalytical Chemistry
出版年：2016
出版时间：1 November 2016
年：2016
卷：780
期：Complete
页码：282-289
全文大小：1198 K

文摘

•: Decamethylferrocene has been studied at microelectrodes in supercritical R32.
•: The natural convection of scR32 can be dampened by using a baffle.
•: The diffusion coefficient of DMFc in scR32 has been determined.
•: A baffled macroelectrode was also used and the results compared to simulated data.
•: Studies of cobaltocene complexes led to a fouling of the Pt electrode in scR32.

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