CdS QDs sensitized BiVO4 is developed and applied as the photoanode of QDSCs.
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CdS QDs enhances the visible light response performance of BiVO4.
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The aligned band states between CdS and BiVO4 suppress the carrier recombination.
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Obtained mesoporous structure improves the interfacial carrier transporting.
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CdS/BiVO4 QDSCs display remarkably enhanced power conversion efficiency.
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