Studies on intermolecular interactions in (nitrobenzene + alkoxyethanol) binary mixtures by relative permittivity measurements at T = (293.15, 298.15, 303.15, 308.15, and 313.15) K

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• 作者：Cezary M. Kinart ; ^{ckinart@uni.lodz.pl} ; Aneta ?wikli¨½ska ; Adam Bald ; Zdzis?aw Kinart
• 关键词：Nitrobenzene ; 2-Methoxyethanol ; 2-Ethoxyethanol ; 2-Propoxyethanol ; 2-Butoxyethanol ; Relative permittivity
• 刊名：Journal of Chemical Thermodynamics
• 出版年：2012
• 出版时间：July, 2012
• 年：2012
• 卷：50
• 期：Complete
• 页码：37-42
• 全文大小：243 K

文摘

Relative permittivities, at T = (293.15, 298.15, 303.15, 308.15, and 313.15) K, in the binary mixtures of nitrobenzene with 2-methoxyethanol, 2-ethoxyethanol, 2-propoxyethanol, and 2-butoxyethanol have been measured as a function of composition. From the experimental results, the deviations in the relative permittivity at T = (293.15, 298.15, 303.15, 308.15, and 313.15) K and the excesses of temperature coefficient of relative permittivity at T = 298.15 K from a mole fraction average have been calculated. The results are discussed in terms of intermolecular interactions and structure of studied binary mixtures.