Understanding the generation of methanol synthesis and water gas shift activity over copper-based catalysts - A spatially resolved experimental kinetic study using steady and non-steady state operation under CO/CO<sub>2</sub>/H<sub>2</sub> feeds

网站地图 | English | 公务邮箱

About the library

Background
History
Leadership
Organization

Opening Hours
Collections
Help Via Email

Electronic Information Resources

Understanding the generation of methanol synthesis and water gas shift activity over copper-based catalysts - A spatially resolved experimental kinetic study using steady and non-steady state operation under CO/CO₂/H₂ feeds

详细信息查看全文

作者：S.K. Wilkinson^a ; ^b ; ^{sam.wilkinson@matthey.com" class="auth_mail" title="E-mail the corresponding author} ; L.G.A. van de Water^a ; B. Miller^c ; M.J.H. Simmons^b ; E.H. Stitt^a ; M.J. Watson^a
关键词：Methanol synthesis ; Water gas shift ; Active site ; Micro kinetics ; Steady state ; Transient
刊名：Journal of Catalysis
出版年：2016
出版时间：May 2016
年：2016
卷：337
期：Complete
页码：208-220
全文大小：2353 K

文摘

•: Spatially discretised experiments used to probe activity of Cu-based catalysts.
•: Mechanistically sound kinetic model show for methanol synthesis and WGS reaction.
•: Non-steady state testing shows link between surface species population and activity.
•: CH₃OH synthesis rate constant correlates to Cu surface area of different catalysts.
•: WGS rate constant does not correlate to Cu surface area of different catalysts.

NGLC 2004-2010.National Geological Library of China All Rights Reserved.
Add:29 Xueyuan Rd,Haidian District,Beijing,PRC. Mail Add: 8324 mailbox 100083
For exchange or info please contact us via email.