Interfacially reinforced carbon fiber composites by grafting modified methylsilicone resin

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• 作者：Bo Jiang ; ^{jiangbo5981@hit.edu.cn} ; Tong Zhang ; Liwei Zhao ; Yudong Huang
• 关键词：Carbon fibers ; Methylsilicone resin ; Nano-silica ; Interfacial properties
• 刊名：Composites Science and Technology
• 出版年：2017
• 出版时间：1 March 2017
• 年：2017
• 卷：140
• 期：Complete
• 页码：39-45
• 全文大小：1868 K
• 卷排序：140

文摘

Modified methylsilicone resin (12EO15-MA-SiO2/MSR) containing nano-silica grafted hyperbranched polymer (12EO15-MA-SiO2) was grafted successfully onto carbon fibers (CFs) surface to enhance the interfacial properties of carbon fiber/methylsilicone resin composites. Fourier transform infrared (FTIR) and X-ray photoelectron spectroscopy (XPS) confirmed the chemical bonding nature between 12EO15-MA-SiO2/MSR and CFs. Scanning electron microscopy (SEM) and interfacial shear strength (IFSS) indicated that the surface morphology and interfacial properties of carbon fibers were highly dependent on the concentration of 12EO15-MA-SiO2 and 12EO15-MA-SiO2/MSR. The results showed that the optimal condition was that the concentration of 12EO15-MA-SiO2/MSR was 1%, in which containing 6%-12EO15-MA-SiO2. Furthermore, significant enhancement of interfacial shear strength was achieved in the composites after modified methylsilicone resin introduced on the fiber. The tensile strength of the carbon fibers remained stable after the grafted treatment. Thus, it is a facile and effective interface design strategy to develop multifunctional fibers with desirable properties in industry applications.