文摘
The reaction of the cluster salt K4[Re4Te4(CN)12]¡¤5H2O with NdCl3¡¤6H2O was studied in either an acidic medium (HCl) or in a water solution in the presence of the following organic agents: hexafluoroacetylacetonate, 2,2?bipyridine or 1,10-phenanthroline (m>phenm>). The crystal structures of four new compounds have been solved by single crystal X-ray diffraction analysis: (H)[{Nd(H2O)5}{Re4Te4(CN)12}]¡¤5.5H2O (1) (space group m>Pm>21/m>cm>, framework structure), K2[{Nd(H2O)7}2{Re4Te4(CN)12}2]¡¤8H2O (2) (space group m>§³m>2/m>cm>, isolated structure), K0.5H0.5[{Nd(H2O)5}{Re4Te4(CN)12}]¡¤3H2O (3) (space group m>§³mcmm>, layered structure) and (m>phenm>H)[{Nd(H2O)2(m>phenm>)2}{Re4Te4(CN)12}]¡¤11H2O (4) (space group m>§³m>2/m>cm>, chain structure). 1,10-Phenanthroline was found to have been incorporated into the structure of compound 4, whilst hexafluoroacetylacetonate and 2,2?bipyridine did not enter the structures of 2 and 3. It was shown that the structures of compounds 2-4 differ dramatically from that found for compound 1, which was obtained in the absence of the organic agents.
