Unsymmetrical coordinated Ag(I)-olefin complex based on exo-7-oxabicyclo-[2.2.1]-5-heptene-2,3-dicarboxylate: Synthesis, structure and electrocatalytical property

详细信息    查看全文

• 作者：Yun Gong ^{gongyun7211@cqu.edu.cn} ; Tao Wu ; Jinghua Li ; Jianhua Lin
• 关键词：Ag(I)&ndash ; olefin complex ; Synthesis ; Exo-7-oxabicyclo-[2.2.1]-5-heptene-2 ; 3-dicarboxylate ; Structure ; Electrocatalytical property
• 刊名：Inorganic Chemistry Communications
• 出版年：2012
• 出版时间：May, 2012
• 年：2012
• 卷：19
• 期：Complete
• 页码：39-42
• 全文大小：522 K

文摘

A silver(I)-olefin complex based on achiral exo-7-oxabicyclo-[2.2.1]-5-heptene-2,3-dicarboxylic acid (H₂L) shows a 3-connected layer with {4.8²}-fes topology, in which unsymmetrical coordinated HL possesses chiral centers. The complex exhibits electrocatalytic activity for generating hydrogen from water.