Group 13th metal-organic frameworks and their role in heterogeneous catalysis

详细信息    查看全文

• 作者：Lina Marí ; a Aguirre-Dí ; az ; Daniel Reinares-Fisac ; Marta Iglesias ; Enrique Gutié ; rrez-Puebla ; Felipe Gá ; ndara ; Natalia Snejko ; ^{snejko@icmm.csic.es} ; M. Á ; ngeles Monge ; ^{amonge@icmm.csic.es}
• 关键词：IL ; ionic liquid ; DEF ; diethylformamide ; DMA ; dimethylacetamid ; DMF ; dimethylformamide ; HEH ; Hantzsch dihydropyridine ; HPP ; 1 ; 3 ; 4 ; 6 ; 7 ; 8-hexahydro-2H-pyrimido[1 ; 2-a]pyrimidine ; TEA ; tetraethylammonium ; TEBA ; triethylbutylammonium bromide ; TPA ; tetrapropylammonium ; H2PPZ ; piperazinium ; 1 ; 2-H2DACH ; 1 ; 2-diaminocyclohexane ; SpMP ; N-spirocyclicmorpholiniumpyrole bromide ; spPP ; N-spirocyclicpiperidiniumpyrole bromide ; dma ; dimethylamine ; 2 ; 2&prime ; -bipy ; 2 ; 2&prime ; -bipyridine ; 4 ; 4&prime ; -bipy ; 4 ; 4&prim
• 刊名：Coordination Chemistry Reviews
• 出版年：2017
• 出版时间：15 March 2017
• 年：2017
• 卷：335
• 期：Complete
• 页码：1-27
• 全文大小：5012 K
• 卷排序：335

文摘

Al-, Ga- and In-MOFs (p-MOFs) are reviewed, including structural features and properties. p-MOFs act as heterogeneous catalysts in many organic reactions. p-MOFs efficiently catalyze multicomponent reactions (MCR). Tuning the metal ratio in multimetal catalytic MOFs affects the outcome of MCRs. A statistical overview correlates synthetic conditions-structure-properties.