文摘
We have studied growth and self-separation of bulk GaN on c-oriented Al2O3 using low temperature (LT) GaN buffer layers. By studying the X-ray diffraction (XRD) signature for the asymmetric and symmetric reflections versus the LT-GaN thickness and V/III precursor ratio, we observe that the peak width of the reflections is minimized using a LT buffer thickness of ¡«100-300 nm. It was observed that the V/III precursor ratio has a strong influence on the morphology. In order to obtain a smooth morphology, the V/III precursor ratio has to be more than 17 during the growth of the buffer layer. By using an optimized LT buffer layer for growth of a 20 ¦Ìm thick GaN layer, we obtain a XRD peak with a full width at half maximum of ¡«400 and ¡«250 arcs for (002) and (105) reflection planes, respectively, and with a dark pit density of ¡«2.2¡Á108 cm?2. For layers thicker than 1 mm, the GaN was spontaneously separated and by utilizing this process, thick free freestanding 2¡å GaN substrates were manufactured.
