An unexpected rearrangement of carbon vertexes in the tricarbollide series. Asymmetrical 7-aryl-nido-7,8,9-C<sub>3</sub>B<sub>8</sub>H<sub>11</sub> derivatives

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An unexpected rearrangement of carbon vertexes in the tricarbollide series. Asymmetrical 7-aryl-nido-7,8,9-C₃B₈H₁₁ derivatives

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作者：Mario Bakardjiev^a ; Josef Holub^a ; Drahom&iacute ; r Hnyk^a ; Bohumil &Scaron ; t&iacute ; br^a ; ^{stibr@iic.cas.cz" class="auth_mail" title="E-mail the corresponding author} ; Zdeňka Růžičková ; ^b ; Ale&scaron ; Růžička^b
关键词：Boron hydrides ; Carboranes ; Tricarbaboranes ; Tricarbollides ; NMR spectroscopy ; Reaction mechanisms
刊名：Journal of Organometallic Chemistry
出版年：2016
出版时间：1 March 2016
年：2016
卷：805
期：Complete
页码：117-121
全文大小：692 K

文摘

•: A new mode of cage rearrangement in the tricarbollide series.
•: Reactions leading to carboranes of the asymmetrically substituted 7-R-nido-7,8,9-C₃B₈H₁₁ series.
•: Additional mechanistic aspects of rearrangement in the 11-vertex nido tricarbaborane cage.

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