Methyl fluoroalkanoate as methyl-transferring reagent. Unexpected participation of B<sub>Al</sub>2 (S<sub>N</sub>2) mechanism in the reaction of methyl 2,3,3,3-tetrafluoro-2-methoxypropanoate with amines

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Methyl fluoroalkanoate as methyl-transferring reagent. Unexpected participation of B_Al2 (S_N2) mechanism in the reaction of methyl 2,3,3,3-tetrafluoro-2-methoxypropanoate with amines

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作者：Bohumil Dolenský ; ^a ; ^{dolenskb@vscht.cz" class="auth_mail" title="E-mail the corresponding author} ; Jaroslav Kv&iacute ; čala^b ; Oldřich Paleta^b
关键词：Methyl tetrafluoropropanoate ; Methyl transfer ; Amine methylation ; BAl2 mechanism ; SN2 mechanism
刊名：Journal of Fluorine Chemistry
出版年：2016
出版时间：May 2016
年：2016
卷：185
期：Complete
页码：31-35
全文大小：415 K

文摘

•: Methyl 2,3,3,3-tetrafluoro-2-methoxypropanoate reacts with amines either via B_Al2 to amides or via B_Al2 to N-methylamines.
•: The reaction pathway depends on the amine nature and the reaction condition.
•: 2,3,3,3-Tetrafluoro-2-methoxypropanoate behaves as a leaving group.

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