Complex formation reactions of gallium(III) and iron(III/II) with l-proline-thiosemicarbazone hybrids: A comparative study

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• 作者：Felix Bacher^a ; ^{felix.bacher@univie.ac.at} ; Orsolya Dö ; mö ; tö ; r^b ; ^c ; ^{domotor.o@chem.u-szeged.hu} ; É ; va A. Enyedy^b ; ^{enyedy@chem.u-szeged.hu} ; Lana Filipović^d ; ^{lanafil82@gmail.com} ; Sini&scaron ; a Radulović^d ; ^{sinisar@ncrc.ac.rs} ; Gregory S. Smith^e ; ^{gregory.smith@uct.ac.za} ; Vladimir B. Arion^a ; ^{vladimir.arion@univie.ac.at}
• 关键词：Thiosemicarbazones ; Gallium(III) ; Iron(III) ; Antiproliferative activity
• 刊名：Inorganica Chimica Acta
• 出版年：2017
• 出版时间：30 January 2017
• 年：2017
• 卷：455
• 期：part_P2
• 页码：505-513
• 全文大小：1272 K
• 卷排序：455

文摘

New gallium(III) and iron(III/II) complexes with l-proline-thiosemicarbazone hybrids were synthesised. Comprehensive characterisation(1D/2D NMR, UV–vis, ESI MS and X-ray crystallography) of gallium(III) and iron(III) complexes. In vitro antiproliferative activity was evaluated. Solution stability of gallium(III) and iron(III/II) complexes investigated by pH-metry, 1H NMR- and UV–vis spectroscopies.