Electron-blocking hole-transport polyterpenol thin films

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• 作者：Mohan V. Jacob^a ; ^{Mohan.Jacob@jcu.edu.au} ; Kateryna Bazaka^a ; Dai Taguchi^b ; Takaaki Manaka^b ; Mitsumasa Iwamoto^b
• 刊名：Chemical Physics Letters
• 出版年：2012
• 出版时间：1 March 2012
• 年：2012
• 卷：528
• 期：Complete
• 页码：26-28
• 全文大小：434 K

文摘

The carrier blocking property of polyterpenol thin films derived from non-synthetic precursor is studied using Electric Field Induced Optical Second Harmonic Generation (EFISHG) technique that can directly probe carrier motion in organic materials. A properly biased double-layer MIM device with a structure of indium zinc oxide (IZO)/polyterpenol/C₆₀/Al shows that by incorporating the polyterpenol thin film, the electron transport can be blocked while the hole transport is allowed. The inherent electron blocking hole transport property is verified using Al/C₆₀/Alq3/polyterpenol/IZO and Al/Alq3/polyterpenol/IZO structures. The rectifying property of polyterpenol is very promising and can be utilized in the fabrication of many organic devices.