Local atomic structural investigations of precursory phenomenon of the hydrogen release from LiAlD4
详细信息    查看全文
文摘
Local atomic structural investigations of LiAlD4, which is composed of Li+ and [AlD4]鈭?/sup>, at 40-300 K were studied by total neutron scattering combined with pair distribution function (PDF) analysis for understanding of hydrogen release from LiAlD4. The results showed that the Al-D pair distribution almost unchanged, while the Li-D pair distribution clearly started to broaden and shrink above 200-250 K. The shrinking of the Li-D pair distribution might lead to the local generation of LiD, which was speculated as the precursory phenomenon for the hydrogen release from LiAlD4.
NGLC 2004-2010.National Geological Library of China All Rights Reserved.
Add:29 Xueyuan Rd,Haidian District,Beijing,PRC. Mail Add: 8324 mailbox 100083
For exchange or info please contact us via email.