Volatile organic compounds abatement over copper-based catalysts: Effect of support

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• 作者：M. Konsolakis^a ; ^{mkonsol@science.tuc.gr} ; S.A.C. Carabineiro^b ; ^{scarabin@fe.up.pt} ; G.E. Marnellos^c ; ^d ; M.F. Asad^b ; O.S.G.P. Soares^b ; M.F.R. Pereira^b ; J.J.M. Ó ; rfã ; o^b ; J.L. Figueiredo^b
• 关键词：Ethyl acetate (EtOAc) oxidation ; Volatile organic compounds (VOCs) ; Copper (Cu)-based catalysts ; CeO2 ; La2O3 ; Gd2O3 ; Sm2O3
• 刊名：Inorganica Chimica Acta
• 出版年：2017
• 出版时间：30 January 2017
• 年：2017
• 卷：455
• 期：part_P2
• 页码：473-482
• 全文大小：3200 K
• 卷排序：455

文摘

Ethyl acetate oxidation was tested over Cu/CeO2, Cu/Gd2O3, Cu/La2O3 and Cu/Sm2O3. A close correlation between the oxidation performance and redox properties was revealed. Cu/CeO2 had the best performance due to its high reducibility and labile oxygen. Complete conversion of ethyl acetate was attained at temperatures lower than 280 °C.