Solubility of RbCl and CsCl in pure water at subzero temperatures, heat capacity of RbCl(aq) and CsCl(aq) at T </ce:hsp>= </ce:hsp>298.15 </ce:hsp>K, and thermodynamic modeling of RbCl </ce:hsp>+ </ce:hsp>H<sub>2</sub>O and CsCl </ce:hsp>+ </ce:hsp>H<sub>2</sub>O systems

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Solubility of RbCl and CsCl in pure water at subzero temperatures, heat capacity of RbCl(aq) and CsCl(aq) at T = 298.15 K, and thermodynamic modeling of RbCl + H₂O and CsCl + H₂O systems

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作者：Dandan Gao^a ; ^b ; Dongdong Li^a ; ^c ; ^{ddong_li@hotmail.com" class="auth_mail" title="E-mail the corresponding author} ; Wu Li^a ; ^c ; ^{driverlaoli@163.com" class="auth_mail" title="E-mail the corresponding author}
关键词：RbCl ; CsCl ; Solubility ; Heat capacity ; Thermodynamic modeling
刊名：Journal of Chemical Thermodynamics
出版年：2017
出版时间：January 2017
年：2017
卷：104
期：Complete
页码：201-211
全文大小：2254 K

文摘

•: Solubility of RbCl(cr) and CsCl(cr) in pure water were determined at subzero temperatures.
•: Specific heat capacity of RbCl(aq) and CsCl(aq) solutions were determined at 298.15 K and concentration to near saturation.
•: Temperature dependent thermodynamic models for RbCl + H₂O and CsCl + H₂O binary systems were developed.
•: The models can represent all the properties of the systems simultaneously with one set parameters.
•: The models have an advantage especially at subzero temperatures.