Characterization of syringyl and guaiacyl lignins in thermomechanical pulp from oil palm empty fruit bunch by pyrolysis-gas chromatography-mass spectrometry using ion intensity calibration

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• 作者：Akiko Nakagawa-Izumi^a ; Yin Ying H&rsquo ; ng^a ; Lilik Tri Mulyantara^a ; ^b ; Roni Maryana^a ; ^c ; Vu Thang Do^a ; Hiroshi Ohi^a ; ^{oi.hiroshi.gm@u.tsukuba.ac.jp}
• 关键词：EFB ; empty fruit bunch ; TMP ; thermomechanical pulp ; Py ; GC/MS pyrolysis-gas chromatography-mass spectrometry ; NBO ; nitrobenzene oxidation ; S ; syringyl ; G ; guaiacyl ; Sa ; syringaldehyde ; Va ; vanillin
• 刊名：Industrial Crops and Products
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：95
• 期：Complete
• 页码：615-620
• 全文大小：771 K
• 卷排序：95

文摘

Thermomechanical pulp (TMP) fabricated from empty fruit bunch (EFB) of oil palm were separated into four fractions. Pyrolysis-gas chromatography mass-spectrometry (Py-GC/MS) indicated chemical feature of lignin in the TMP fractions. Eight lignins pyrolysis products were successfully determined through calibration obtained by total ion intensities. Syringyl/Guaiacyl ratio by Py-GC/MS have a good correlation with syringaldehyde/vanillin ratio by nitrobenzene oxidation.