Probing effective photocorrosion inhibition and highly improved photocatalytic hydrogen production on monodisperse PANI@CdS core-shell nanospheres

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Probing effective photocorrosion inhibition and highly improved photocatalytic hydrogen production on monodisperse PANI@CdS core-shell nanospheres

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作者：Chao Wang^a ; Li Wang^a ; ^b ; Jun Jin^a ; Jing Liu^a ; Yu Li^a ; ^{yu.li@whut.edu.cn" class="auth_mail" title="E-mail the corresponding author} ; ^{manliyu2002@gmail.com" class="auth_mail" title="E-mail the corresponding author} ; Min Wu^a ; Lihua Chen^a ; Binjie Wang^d ; Xiaoyu Yang^a ; Bao-Lian Su^a ; ^b ; ^c ; ^{baoliansu@whut.edu.cn" class="auth_mail" title="E-mail the corresponding author} ; ^{bls26@cam.ac.uk" class="auth_mail" title="E-mail the corresponding author} ; ^{bao-lian.su@unamur.be" class="auth_mail" title="E-mail the corresponding author}
关键词：PANI ; CdS ; Core-shell nanospheres ; Photocorrosion inhibition ; Photocatalytic hydrogen production
刊名：Applied Catalysis B: Environmental
出版年：2016
出版时间：5 July 2016
年：2016
卷：188
期：Complete
页码：351-359
全文大小：3240 K

文摘

•: PANI@CdS core-shell nanospheres via a proton doped in-situ polymerization technique.
•: PANI@CdS core-shell nanospheres demonstrate highly enhanced photocorrosion inhibition and photocatalytic hydrogen production.
•: CS and/or NCd bonds are newly formed between PANI shell and CdS core, leading to enhanced photocorrosion inhibition.
•: The photogenerated holes migrate from VB of CdS to HOMO of PANI, leading to enhanced photocatalytic hydrogen production.

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