Chemical fixation and conversion of CO₂ into cyclic and cage-type metal carbonates

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• 作者：Katarzyna Sołtys-Brzostek^a ; ¹ ; Michał Terlecki^b ; ¹ ; Kamil Sokołowski^a ; ¹ ; Janusz Lewiński^a ; ^b ; ^{lewin@ch.pw.edu.pl}
• 关键词：Ac ; acetate ; CA ; carbonic anhydrase ; DEF ; N ; N&prime ; -diethylformamide ; DME ; dimethyl ether ; DMF ; N ; N&prime ; -dimethylformamide ; DMSO ; dimethyl sulfoxide ; Et ; Ethyl ; i-Pr ; iso-propyl ; Ln ; lanthanide ; Me ; methyl ; n-Bu ; n-butyl ; OTf ; trifluoromethanesulfonate ; Ph ; phenyl ; Piv ; pivalate ; RE ; rare earth ; t-Bu ; tert-butyl ; THF ; tetrahydrofuran
• 刊名：Coordination Chemistry Reviews
• 出版年：2017
• 出版时间：1 March 2017
• 年：2017
• 卷：334
• 期：Complete
• 页码：199-231
• 全文大小：12238 K
• 卷排序：334

文摘

A comprehensive overview of the structural diversity of metal clusters derived from CO2 fixation. Chemical fixation of CO2 as a powerful way leading to multinuclear metal complexes. Carbonate ligands as a building units of macrocyclic systems and closed polyhedrons. The unique features of carbonate anion make it a universal templating agent of metal centers. Encapsulation of carbonate anion within multimetallic polyhedral structures.