Synthesis, characterization and reactivity of vanadium, chromium, and manganese PNP pincer complexes

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• 作者：Matthias Mastalir^a ; Mathias Glatz^a ; Berthold Stö ; ger^b ; Matthias Weil^b ; Ernst Pittenauer^b ; G&uuml ; nter Allmaier^b ; Karl Kirchner^a ; ^{kkirch@mail.tuwien.ac.at}
• 关键词：Vanadium ; Chromium ; Manganese ; Pincer ligands ; Homo coupling
• 刊名：Inorganica Chimica Acta
• 出版年：2017
• 出版时间：30 January 2017
• 年：2017
• 卷：455
• 期：part_P2
• 页码：707-714
• 全文大小：2152 K
• 卷排序：455

文摘

The synthesis and characterization of new V, Cr, and Mn PNP pincer is reported. Fragmentation of all complexes is investigated by means of ESI-MS. Structures of complexes were determined by X-ray single crystal analyses. These complexes catalyze the oxidative homo-coupling of aryl Grignard reagents.