Binuclear tetra-acetate bridged Gd(III) complex [Gd<sub>2</sub>(μ<sub>2</sub>-O<sub>2</sub>CMe)<sub>4</sub>(H<sub>2</sub>L)<sub>2</sub>](ClO<sub>4</sub>)<sub>2</sub>·2H<sub>2</sub>O·2MeOH (H<sub>2</sub>L </ce:hsp>= </ce:hsp>bis(5-methylimidazol-4-yl-methylideneaminopropyl)methylamine): Synthesis, structure, and magnetic properties

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Binuclear tetra-acetate bridged Gd(III) complex [Gd₂(μ₂-O₂CMe)₄(H₂L)₂](ClO₄)₂·2H₂O·2MeOH (H₂L = bis(5-methylimidazol-4-yl-methylideneaminopropyl)methylamine): Synthesis, structure, and magnetic properties

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作者：Makoto Ito^a ; Daisuke Hamada^a ; Hiromasa Ono^a ; Naohide Matsumoto^a ; ^{naohide@aster.sci.kumamoto-u.ac.jp" class="auth_mail" title="E-mail the corresponding author} ; Yukinari Sunatsuki^b ; Nazzareno Re^c
关键词：Binuclear GdIII complex ; Tetra-acetate bridge ; Magnetic interaction
刊名：Inorganica Chimica Acta
出版年：2016
出版时间：24 March 2016
年：2016
卷：443
期：Complete
页码：274-278
全文大小：865 K

文摘

•: Binuclear tetra-acetate bridged Gd^III complex was synthesized.
•: Linear tetradentate ligand coordinates to two Gd^III ions.
•: Two Gd^III ions are bridged by four acetate groups in η¹:η¹:μ₂ and η²:η¹:μ₂ fashions.
•: Anti-ferromagnetic Gd^III–Gd^III interaction is operating.

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