Complexes of rhodium and platinum with 4,6-dinitro-5,7-dihydroxybenzo[1,2-c][1,2,5]oxadiazole 1-oxide

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• 作者：Elena V. Guseva ; ^{leylaha@mail.ru} ; Tatyana M. Buslaeva ^{buslaevatm@mail.ru}
• 关键词：RhCl3· ; nH2O ; PtCl4 ; Disodium complex of 4 ; 6-dinitro-5 ; 7-dihydroxybenzo[1 ; 2-c][1 ; 2 ; 5]oxadiazole 1-oxide ; Synthesis ; Rhodium complex ; Macrocyclization ; Platinum complex ; Redox process ; Quantum-chemical modeling
• 刊名：Inorganica Chimica Acta
• 出版年：2017
• 出版时间：30 January 2017
• 年：2017
• 卷：455
• 期：part_P2
• 页码：455-464
• 全文大小：1363 K
• 卷排序：455

文摘

Rh4III(C6N4O8)4Сl162·Rh26IIIСl9·3Н2О is polynuclear-polyligand rhodium complex. PtII(НС6N4O8)Cl·Н2О·10Н2О is mononuclear-monoligand complex. Changes in the oxidation state of ion RhIII in complexing are not observed. We note the reduction of PtIV → PtII and coordination of ligand to ion PtII.