Layered crystalline chiral salen Mn(III) complexes immobilized on organic polymer-inorganic hybrid zinc phosphonate-phosphate as efficient and reusable catalysts for the unfunctionalized olefin epoxidation

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Layered crystalline chiral salen Mn(III) complexes immobilized on organic polymer-inorganic hybrid zinc phosphonate-phosphate as efficient and reusable catalysts for the unfunctionalized olefin epoxidation

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作者：Jing Huang^a ; ^b ; ^{hj41012@163.com" class="auth_mail" title="E-mail the corresponding author} ; Li Yuan^a ; Jiali Cai^c ; Xiaohong Chen^a ; Dengwei Qi^d
关键词：Asymmetric epoxidation ; Unfunctionalized olefins ; Jacobsen's catalyst ; Heterogeneous catalyst ; Alkyldiamines
刊名：Inorganic Chemistry Communications
出版年：2016
出版时间：March 2016
年：2016
卷：65
期：Complete
页码：4-8
全文大小：710 K

文摘

•: The chiral salen Mn(III) is immobilized on alkyldiamines modified ZnPS-PVPA.
•: The heterogeneous catalysts display superior activity according to the homogeneous catalysts.
•: The heterogeneous catalysts could be reused at least nine times without significant loss of activity.
•: The catalysts could be used in large-scale reactions with superior catalytic disposition.

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