Chemistry of the highly stable hindered cobalt sandwich compound (η<sup>5</sup>-Cp)Co(η<sup>4</sup>-C<sub>4</sub>Ph<sub>4</sub>) and its derivatives

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Chemistry of the highly stable hindered cobalt sandwich compound (η⁵-Cp)Co(η⁴-C₄Ph₄) and its derivatives

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作者：Dheeraj Kumar ; Mayukh Deb ; Jatinder Singh ; Nem Singh ; Karunesh Keshav ; Anil J. Elias ; ^{eliasanil@gmail.com" class="auth_mail" title="E-mail the corresponding author}
关键词：Cb ; cyclobutadiene ; COD ; cyclooctadiene ; Cp ; cyclopentadienyl ; TPAP ; tetrapropylammonium perruthenate ; NMO ; N-methyl morpholine N-oxide ; HWE ; Horner Wadsworth Emmons ; Cbz ; carboxybenzyl ; NLO ; nonlinear optical ; OMO ; oligonucleotide modified organometallics ; NBS ; N-bromosuccinimide ; DFT ; density functional theory ; ATP ; adenosine tri-phosphate ; DMF ; N ; N-dimethylformamide ; Fc ; ferrocene ; QCA ; quantum cellular automata ; PDI ; polydispersity index ; COP ; cobalt oxazoline palladacycle ; DNP ; dinitropheny
刊名：Coordination Chemistry Reviews
出版年：2016
出版时间：1 January 2016
年：2016
卷：306
期：part_P1
页码：115-170
全文大小：4282 K

文摘

•: First review on (η⁵-Cp)Co(C₄R₄) type complexes.
•: High stability, good solubility and ease of synthesis similar to ferrocene.
•: Methods to derivatize a highly unreactive cyclopentadienyl ring.
•: Basal bulkiness induced asymmetric catalysis.
•: Catalysts for Aza-Claisen rearrangement.

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