Mechanical alloying as a new synthesis route for metastable silicon clathrates

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Mechanical alloying as a new synthesis route for metastable silicon clathrates

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作者：Adrien Moll^a ; Mickael Beaudhuin^a ; ^{mickael.beaudhuin@umonptellier.fr" class="auth_mail" title="E-mail the corresponding author} ; Vincent Legrand^a ; Ré ; gis Debord^b ; Sté ; phane Pailhè ; s^b ; Romain Viennois^a ; ^{romain.viennois@umontpellier.fr" class="auth_mail" title="E-mail the corresponding author} ; Nicole Fré ; ty^a
关键词：Intermetallic alloys and compounds ; Phase transformation ; Powder technology ; Metallurgy ; X-Ray techniques ; Raman
刊名：Materials Letters
出版年：2017
出版时间：15 January 2017
年：2017
卷：187
期：Complete
页码：1-3
全文大小：386 K

文摘

•: DFT calculation has shown that Ba₂₄Si₁₀₀ is the most stable among Ba-Si clathrates.
•: MA enabled to obtain for the first time one metastable clathrate: Ba₂₄Si_100.
•: Up to 90% purity of Ba₂₄Si₁₀₀ has been obtained in the crystalline phase.

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