Insights into the accessibility of Zr in Zr/SBA-15 mesoporous silica supports with increasing Zr loadings

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Insights into the accessibility of Zr in Zr/SBA-15 mesoporous silica supports with increasing Zr loadings

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作者：Masaru Ogura^a ; Remy Guillet-Nicolas^b ; Dalil Brouri^c ; Sandra Casale^c ; Juliette Blanchard^c ; Katie A. Cychosz^b ; Matthias Thommes^b ; Cyril Thomas^c ; ^{cyril.thomas@upmc.fr" class="auth_mail" title="E-mail the corresponding author}
关键词：NOx-TPD ; ZrO2 ; ZrSiO4 ; SEM ; TEM
刊名：Microporous and Mesoporous Materials
出版年：2016
出版时间：1 May 2016
年：2016
卷：225
期：Complete
页码：440-449
全文大小：3906 K

文摘

•: Zr deposition in SBA-15 porosity is comprehensively understood using N₂ sorption.
•: 15">Zr accessibility is found to decrease to a significant extent up to 2 Zr atoms/nm².
•: ZrSiO₄ is found to form above 2 Zr atoms/nm².

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