Prediction of solid solute solubility in supercritical carbon dioxide with organic cosolvents from the PR+COSMOSAC equation of state

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Prediction of solid solute solubility in supercritical carbon dioxide with organic cosolvents from the PR+COSMOSAC equation of state

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作者：Yi-Shiu Ting ; Chieh-Ming Hsieh ; ^{hsiehcm@ncu.edu.tw" class="auth_mail" title="E-mail the corresponding author}
关键词：Solubility ; Supercritical carbon dioxide ; Cosolvent ; PR+COSMOSAC EOS ; Prediction
刊名：Fluid Phase Equilibria
出版年：2017
出版时间：15 January 2017
年：2017
卷：431
期：Complete
页码：48-57
全文大小：1388 K

文摘

•: PR+COSMOSAC EOS is applied to predict solid solute solubility in ScCO₂ + cosolvent.
•: The overall deviation in ALD-x is 0.76 for 23 solid solutes.
•: The melting temperature and heat of fusion of a solute are the only experimental inputs.
•: The method is useful tool for cosolvent screening in ScCO₂ system.

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