Low temperature structural modification in Rb<sub>2</sub>ZrF<sub>6</sub>: Investigations by perturbed angular correlation spectroscopy

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Low temperature structural modification in Rb₂ZrF₆: Investigations by perturbed angular correlation spectroscopy

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作者：S.K. Dey ^{skumar.dey@saha.ac.in" class="auth_mail" title="E-mail the corresponding author} ; C.C. Dey ; ^{chandicharan.dey@saha.ac.in" class="auth_mail" title="E-mail the corresponding author} ; S. Saha ^{satyajit.saha@saha.ac.in" class="auth_mail" title="E-mail the corresponding author}
关键词：Inorganic compounds ; Chemical synthesis ; Crystal structure ; Phase transitions
刊名：Journal of Physics and Chemistry of Solids
出版年：2016
出版时间：June 2016
年：2016
卷：93
期：Complete
页码：145-156
全文大小：3907 K

文摘

•: Crystalline compounds Rb₂ZrF₆ and Cs₂HfF₆ have been studied by TDPAC.
•: We have found four different structural modifications of Rb₂ZrF₆.
•: Two new structures have been found at room temperature.
•: Different structural modifications in Rb₂ZrF₆ probably arise due to rotation of the octahedral ionic group ZrF₆²⁻.
•: For the analogues compound Cs₂HfF₆, only two structural modifications have been found.

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