Mesoporous TiO2 (meso-TiO2) had the larger pore channel than MCM-41.
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Polyethylenimine (PEI) were modified on meso-TiO2 surface and inner-channel.
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Appropriate molecular mass of PEI treated meso-TiO2 had great barrier property.
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Meso-TiO2/PEI prolonged the path of water molecules diffusing into the coatings.
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Meso-TiO2/PEI structure enhanced epoxy coating barrier and anticorrosion property.
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