Coordination complexes of copper(II) with herbicide-trichlorophenoxyacetate: Syntheses, characterization, single crystal X-ray structure and packing analyses of monomeric [Cu(γ-pic)₃(2,4,5-trichlorophenoxyacetate)]·H₂O, [trans-Cu(en)₂(2,4,5-trichlorophenoxyacetate)₂]·2H₂O and dimeric [Cu_2<

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• 作者：Raj Pal Sharma^a ; ^{rpsharmapu@yahoo.co.in} ; Anju Saini^a ; Jitendra Kumar^a ; Santosh Kumar^a ; Paloth Venugopalan^a ; Valeria Ferretti^b ; ^frt@unife.it
• 关键词：Copper(II) complex ; 2 ; 4 ; 5-Trichlorophenoxyacetate ; γ-Picoline ; Ethylenediamine ; Triethanolamine ; X-ray crystallography
• 刊名：Inorganica Chimica Acta
• 出版年：2017
• 出版时间：1 March 2017
• 年：2017
• 卷：457
• 期：Complete
• 页码：59-68
• 全文大小：2052 K
• 卷排序：457

文摘

Three novel hybrid copper(II) 2,4,5-trichlorophenoxyacetate complexes were synthesized. Crystal lattice is stabilized by array of non-covalent interactions. All complexes show similar mode of carboxylate coordination (monodentate). Variety of structural frameworks in presence of different ligands. Complex 2 shows dual nature (ionic in solution state and covalent in solid state).