Ru-catalyzed ortho-oxidative alkenylation of 2-arylbenzo[d]thiazoles in aqueous solution of anionic surfactant sodium dodecylbenzenesulfonate (SDBS)

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• 作者：Yuanyuan Ping ; Zhaobin Chen ; Qiuping Ding ; ^{dqpjxnu@gmail.com} ; Qiang Zheng ; Yuqing Lin ; Yiyuan Peng
• 关键词：Alkenylation ; C&ndash ; H functionalization ; 2-arylbenzo[d]thiazoles ; 2-arylthiazoles ; Aqueous
• 刊名：Tetrahedron
• 出版年：2017
• 出版时间：2 February 2017
• 年：2017
• 卷：73
• 期：5
• 页码：594-603
• 全文大小：968 K
• 卷排序：73

文摘

A mild and efficient Ru-catalyzed ortho-oxidative alkenylation of 2-arylbenzo[d]thiazoles through twofold C-H bond functionalization in aqueous solution of anionic surfactant sodium dodecylbenzenesulfonate (SDBS) has been developed using activated olefins as coupling partner. The protocol could be carried out smoothly on a gram scale, recyclable, and applicable to 2-arylthiazoles.