Anionic Guests in Prismatic Cavities Generated by Enneanuclear Nickel Metallacycles

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• 作者：Jordi Esteban ; Mercè Font-Bardia ; Albert Escuer
• 刊名：Inorganic Chemistry
• 出版年：2014
• 出版时间：January 21, 2014
• 年：2014
• 卷：53
• 期：2
• 页码：1113-1121
• 全文大小：518K
• ISSN：1520-510X

文摘

The combination of polydentate aminated ligands with the 2-pyridyloxime-nickel-azide system leads to series of clusters with unprecedented topologies. Among them, a remarkable family of {Ni₉} metallacycles that are capable of selective encapsulation of azide/halide anions in a cryptand-like cavity through hydrogen-bond interactions has been characterized.