Semiconductor nanowires have achieved great attention for integration in next-generation electronics. However, for nanowires with diameters compara
ble to the De
bye length, which would generally
be required for one-dimensional operation, surface states degrade the device performance and increase the low-frequency noise. In this study, single In
b>2b>O
b>3b> nanowire transistors were fa
bricated and characterized
before and after surface passivation with a self-assem
bled monolayer of 1-octadecanethiol (ODT). Electrical characterization of the transistors shows that device performance can
be enhanced upon ODT passivation, exhi
biting steep su
bthreshold slope (64 mV/dec), near zero threshold voltage (0.6 V), high mo
bility (624 cm
2/V路s), and high on-currents (40 渭A). X-ray photoelectron spectroscopy studies of the ODT-passivated nanowires indicate that the molecules are
bound to In
b>2b>O
b>3b> nanowires through the thiol linkages. Device simulations using a rectangular geometry to represent the nanowire indicate that the improvement in su
bthreshold slope and positive shift in threshold voltage can
be explained in terms of reduced interface trap density and changes in fixed charge density. Flicker (low-frequency, 1/
f) noise measurements show that the noise amplitude is reduced following passivation. The interface trap density
before and after ODT passivation is profiled throughout the
band gap energy using the su
bthreshold current鈥搗oltage characteristics and is compared to the values extracted from the low-frequency noise measurements. The results indicate that self-assem
bled monolayer passivation is a promising optimization technology for the realization of low-power, low-noise, and fast-switching applications such as logic, memory, and display circuitry.<
br>
Keywords:
bs.acs.org/action/doSearch?action=search&searchText=octadecanethiol&qsSearchArea=searchText">octadecanethiol; bs.acs.org/action/doSearch?action=search&searchText=indium+oxide&qsSearchArea=searchText">indium oxide; bs.acs.org/action/doSearch?action=search&searchText=nanowires&qsSearchArea=searchText">nanowires; bs.acs.org/action/doSearch?action=search&searchText=flicker+noise&qsSearchArea=searchText">flicker noise; bs.acs.org/action/doSearch?action=search&searchText=transistor&qsSearchArea=searchText">transistor