Synthesis, Photophysics, Electrochemistry, Theoretical, and Transient Absorption Studies of Luminescent Copper(I) and Silver(I) Diynyl Complexes. X-ray Crystal Structures of [Cu3( 详细信息    查看全文

• 作者：Wing-Yin Lo ; Chi-Ho Lam ; Vivian Wing-Wah Yam ; Nianyong Zhu ; Kung-Kai Cheung ; Sofiane Fathallah ; Sabri Messaoudi ; Boris Le Guennic ; Samia Kahlal ; and Jean-Franç ; ois Halet
• 刊名：Journal of the American Chemical Society
• 出版年：2004
• 出版时间：June 16, 2004
• 年：2004
• 卷：126
• 期：23
• 页码：7300 - 7310
• 全文大小：370K
• 年卷期：v.126,no.23(June 16, 2004)
• ISSN：1520-5126

文摘

A series of soluble trinuclear copper(I) and silver(I) complexes containing bicapped diynyl ligands,[M₃(-dppm)₃(₃-¹-CCCCR)₂]PF₆ (M = Cu, R = Ph, C₆H₄-CH₃-p, C₆H₄-OCH₃-p, ⁿC₆H₁₃, H; M = Ag,R = Ph, C₆H₄-OCH₃-p), has been synthesized and their electronic, photophysical, and electrochemicalproperties studied. The X-ray crystal structures of [Cu₃(-dppm)₃(₃-¹-CCCCPh)₂]PF₆ and [Cu₃(-dppm)₃(₃-¹-CCCCH)₂]PF₆ have been determined.